Seawater Chemistry 101: Salinity, pH and Alkalinity
Why the sea is salty, why it's slightly alkaline, and why its pH is drifting. A gentle but rigorous introduction to the chemistry that rules marine life.
Dr. Lena Fischer ·
Why is the sea salty, why is some sea fresher than the rest, and why does salt settle into layers? The ocean's salt budget and haloclines, explained.
A litre of seawater carries about 35 grams of dissolved salt — roughly a heaped tablespoon — and the ocean holds enough of it to bury the planet's land under a 150-metre layer. Yet almost nobody can say why the sea is salty, why some parts of it are noticeably fresher than others, or why estuaries stack fresh water on top of salt in layers you can sometimes see with your own eyes. Salinity is one of the two properties (with temperature) that define a body of seawater: it sets the density, organises the layering, and decides which organisms can live where. Here is how the ocean's salt budget works.
Rain is nearly pure water. But it is also a weak acid — carbon dioxide from the air dissolves into it, forming dilute carbonic acid — and as it runs over and through rock it dissolves minerals: sodium, calcium, magnesium, potassium. Rivers carry those dissolved ions to the sea. Water then evaporates from the ocean surface, but the ions do not; evaporation is a one-way export of pure water that leaves everything else behind. Over geological time, the ocean has been a collecting pan for dissolved rock.
Two refinements complete the story:
We cover the broader chemical picture — pH, alkalinity, the carbonate system — in Seawater Chemistry 101. The practical scale: open-ocean salinity ranges roughly from 32 to 37 grams of salt per kilogram of seawater, with a global average near 35. Oceanographers now report it on a unitless "practical salinity" scale derived from conductivity, but thinking in grams per kilogram is fine.
If the salt recipe is constant, what varies is the freshwater balance at the surface. Salinity maps of the world ocean are, to first order, maps of evaporation minus precipitation:
Landlocked seas exaggerate the pattern: the Mediterranean and Red Sea, evaporating under dry skies with narrow connections, run salty; the Baltic, ringed by rivers and rain, is barely brackish — fresher than some lakes are salty.
Sea ice adds a local twist. When seawater freezes, the ice excludes most salt, which drains downward as dense, extremely salty brine — a seasonal salinity engine that helps drive deep currents around the poles (see Sea Ice Explained).
Salt makes water denser, and denser water sinks. Add a source of fresh water — a river, rain, melting ice — and you get one of the sea's most universal structures: fresh or brackish water floating over salt water, separated by a halocline, a layer of rapid salinity change with depth.
Haloclines range from subtle to theatrical:
Salinity rarely acts alone. Because both temperature and salt control density, a halocline usually pairs with a thermocline to form a pycnocline — the density step that divides the ocean into a mixed surface layer and the deep. The dynamics of that layering, and why it caps the nutrient supply that kelp forests depend on, is the subject of Thermoclines, Haloclines and Pycnoclines and Ocean Stratification.
In extreme cases haloclines become visible: where poorly mixed fresh and salt water meet, light bends differently through each layer and divers see a shimmering, oily-seeming boundary — the blurred world of a brackish surface lens, familiar to anyone who has dived a fjord or a river mouth after rain.
You cannot practically weigh the salt in every sample, so oceanographers use proxies. The modern standard measures conductivity — salty water conducts electricity better — with a CTD instrument lowered through the water column (The CTD Cast describes the instrument and the profiles it returns). Autonomous platforms extend the net: Argo floats have built a global, continuous record of upper-ocean salinity, and satellites can now estimate surface salinity from space by measuring microwave emission, which shifts slightly with salt content.
For marine life, salinity is not an abstract number — it is an osmotic fact of life. Water moves across membranes toward the saltier side, so every coastal organism either regulates its internal chemistry against the surroundings (at metabolic cost) or conforms to them (and dies if they swing too far).
That physics draws hard boundaries:
Salinity also touches the carbonate chemistry of ocean acidification: alkalinity and salinity track together across most of the ocean, so salinity maps quietly inform the buffering capacity of coastal water.
Because surface salinity records the balance of evaporation and rain, it is a sensitive gauge of the water cycle. Long records and the Argo era show a coherent pattern: salty regions getting saltier, fresh regions fresher — an amplification of the global hydrological cycle in a warming world, where warmer air holds and moves more moisture. The details are still being refined, but salinity has become one of the clearest fingerprints of climate change in the ocean, written in the oldest property of seawater there is.
On average about 35 grams of dissolved salt per kilogram of seawater — often written as 35 PSU or "35 practical salinity units". Open-ocean values run from roughly 32 to 37; the Red Sea exceeds 40, while the Baltic's surface can drop into single digits.
No — it has been roughly steady for a very long time. Inputs from rivers and vents are balanced by removal processes (sea-salt spray, evaporite deposits, seafloor reactions), so ion residence times are long but finite.
Mainly because evaporation over the Atlantic exceeds its rainfall and river input, and trade winds carry much of that moisture west across Central America into the Pacific — a persistent freshwater export from one basin to the other.
Often, yes. Where fresh and salt water meet without mixing, the differing density bends light differently, producing a shimmering, blurred interface — dramatic in fjords, caves with freshwater lenses, and river mouths after heavy rain.
Directly. Most kelps are stenohaline — adapted to stable, near-oceanic salinity. Prolonged freshening from flood plumes or runoff stresses them physiologically, while the stratification that freshwater adds can also alter light and nutrient supply to the canopy.
Why the sea is salty, why it's slightly alkaline, and why its pH is drifting. A gentle but rigorous introduction to the chemistry that rules marine life.
Dr. Lena Fischer ·
Thermoclines, haloclines and pycnoclines are the invisible boundaries that slice the sea into layers. What they are, how they form, and why they run coastal life.
Dr. Lena Fischer ·
Estuaries layer fresh water over salt in shifting gradients. How estuarine circulation works, where kelp's brackish limit lies, and why the river–sea edge matters.
Dr. Theo Nakamura ·